Europium (Eu3+) and Terbium (Tb3+) singly doped and double doped with Silicon dioxide (SiO2) is synthesized successfully by the sol-gel process. A xenon lamp light source with wavelength, Îģe= 370 nm is used for exciting the sample. The excitation spectra of Eu3+ ion may show applications in the area of UVB, near UVA and green light regions. Magnetic-dipole transition (5D0â7F1) is the dominant transition in emission spectra of Eu3+ ion. The emission spectra of Tb3+ ion reveal four strong emission peaks at 488nm, 545nm, 586nm and 623nm due to the transitions of 5D4â7F6, 5D4â7F5, 5D4â7F4 and 5D4â7F3 respectively with the transition 5D4â7F5 (green emission) as the most intense. The excitation of their co-doped spectra also evident that there is transfer of energy from Tb3+ ion to Eu3+ ion in silicon dioxide.